Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022479077> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2022479077 endingPage "6685" @default.
- W2022479077 startingPage "6679" @default.
- W2022479077 abstract "This paper presents the first electrochemical study of Ni(II) secochlorins, chlorophin, and homoporphyrins and demonstrates the influence of macrocycle-rigidity on the site of electroreduction. Oxidations and reductions were investigated by cyclic voltammetry. The measured electrode potentials were found to be dependent on the nature of the substituents attached to the porphyrinic moiety and on the ring flexiblitiy. The voltammetric behavior of these molecules when employed as catalysts for the electrochemical catalytic debromination of trans-1,2-dibromocyclohexane was used to determine whether reduction peaks were due to a metal-based (formation of catalytically active Ni(I) complexes) or ligand-based (formation of catalytically less active π-anion radical) reduction. The results showed that the homoporphyrins formed ligand-based reduction products. The homoporphyrins are locked into a nonplanar conformation stabilizing the small Ni(II) ion which results in their inability to accommodate the larger Ni(I)..." @default.
- W2022479077 created "2016-06-24" @default.
- W2022479077 creator A5052068845 @default.
- W2022479077 creator A5054142253 @default.
- W2022479077 creator A5089718436 @default.
- W2022479077 date "2000-06-30" @default.
- W2022479077 modified "2023-10-16" @default.
- W2022479077 title "Nickel(II) <i>m</i><i>eso</i>-Tetraphenyl-Homoporphyrins, -secochlorins, and -chlorophin: Control of Redox Chemistry by Macrocycle Rigidity" @default.
- W2022479077 cites W1522909370 @default.
- W2022479077 cites W1968290238 @default.
- W2022479077 cites W1974025162 @default.
- W2022479077 cites W1982097962 @default.
- W2022479077 cites W1988834065 @default.
- W2022479077 cites W1995256996 @default.
- W2022479077 cites W2016034432 @default.
- W2022479077 cites W2019445171 @default.
- W2022479077 cites W2022916467 @default.
- W2022479077 cites W2023348583 @default.
- W2022479077 cites W2029125787 @default.
- W2022479077 cites W2033990981 @default.
- W2022479077 cites W2053372707 @default.
- W2022479077 cites W2054324010 @default.
- W2022479077 cites W2063079716 @default.
- W2022479077 cites W2068100549 @default.
- W2022479077 cites W2075860019 @default.
- W2022479077 cites W2080687554 @default.
- W2022479077 cites W2092181132 @default.
- W2022479077 cites W2093871271 @default.
- W2022479077 cites W2105056426 @default.
- W2022479077 cites W2130271590 @default.
- W2022479077 cites W2167590372 @default.
- W2022479077 cites W2333065922 @default.
- W2022479077 cites W2953273965 @default.
- W2022479077 cites W3139373362 @default.
- W2022479077 cites W4244238393 @default.
- W2022479077 doi "https://doi.org/10.1021/ja000749+" @default.
- W2022479077 hasPublicationYear "2000" @default.
- W2022479077 type Work @default.
- W2022479077 sameAs 2022479077 @default.
- W2022479077 citedByCount "47" @default.
- W2022479077 countsByYear W20224790772012 @default.
- W2022479077 countsByYear W20224790772013 @default.
- W2022479077 countsByYear W20224790772014 @default.
- W2022479077 countsByYear W20224790772015 @default.
- W2022479077 countsByYear W20224790772016 @default.
- W2022479077 countsByYear W20224790772017 @default.
- W2022479077 countsByYear W20224790772018 @default.
- W2022479077 countsByYear W20224790772019 @default.
- W2022479077 countsByYear W20224790772022 @default.
- W2022479077 countsByYear W20224790772023 @default.
- W2022479077 crossrefType "journal-article" @default.
- W2022479077 hasAuthorship W2022479077A5052068845 @default.
- W2022479077 hasAuthorship W2022479077A5054142253 @default.
- W2022479077 hasAuthorship W2022479077A5089718436 @default.
- W2022479077 hasConcept C127413603 @default.
- W2022479077 hasConcept C160343418 @default.
- W2022479077 hasConcept C178790620 @default.
- W2022479077 hasConcept C179104552 @default.
- W2022479077 hasConcept C185592680 @default.
- W2022479077 hasConcept C504270822 @default.
- W2022479077 hasConcept C55904794 @default.
- W2022479077 hasConcept C66938386 @default.
- W2022479077 hasConceptScore W2022479077C127413603 @default.
- W2022479077 hasConceptScore W2022479077C160343418 @default.
- W2022479077 hasConceptScore W2022479077C178790620 @default.
- W2022479077 hasConceptScore W2022479077C179104552 @default.
- W2022479077 hasConceptScore W2022479077C185592680 @default.
- W2022479077 hasConceptScore W2022479077C504270822 @default.
- W2022479077 hasConceptScore W2022479077C55904794 @default.
- W2022479077 hasConceptScore W2022479077C66938386 @default.
- W2022479077 hasIssue "28" @default.
- W2022479077 hasLocation W20224790771 @default.
- W2022479077 hasOpenAccess W2022479077 @default.
- W2022479077 hasPrimaryLocation W20224790771 @default.
- W2022479077 hasRelatedWork W2021099451 @default.
- W2022479077 hasRelatedWork W2053866498 @default.
- W2022479077 hasRelatedWork W2169483994 @default.
- W2022479077 hasRelatedWork W2312579622 @default.
- W2022479077 hasRelatedWork W2322840078 @default.
- W2022479077 hasRelatedWork W2408218962 @default.
- W2022479077 hasRelatedWork W2936188404 @default.
- W2022479077 hasRelatedWork W2952478468 @default.
- W2022479077 hasRelatedWork W4232552561 @default.
- W2022479077 hasRelatedWork W2462484134 @default.
- W2022479077 hasVolume "122" @default.
- W2022479077 isParatext "false" @default.
- W2022479077 isRetracted "false" @default.
- W2022479077 magId "2022479077" @default.
- W2022479077 workType "article" @default.