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- W2022483131 abstract "Abstract The electron-transfer quenching of the luminescence emission of Ru(bpy) 3 2+ (bpy = 2,2′-bipyridine) by CoSiW 11 O 39 H 2 O 6− has been studied by steady-state and pulsed techniques. Both static and dynamic quenching were observed. The luminescence emission was found to decrease with time according to two distinct exponential decays. A kinetic analysis of the system shows that the faster decay corresponds to the intramolecular electron transfer rate constant within the =Ru(bpy) 3 2+ -polytungstate ion pair and that the slower decay is related to the dynamic quenching." @default.
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- W2022483131 date "1985-09-01" @default.
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- W2022483131 title "Photoinduced electron transfer within ion pairs. Direct measure of the intramolecular electron-transfer quenching constant" @default.
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- W2022483131 doi "https://doi.org/10.1016/0009-2614(85)80456-5" @default.
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