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- W2022489938 abstract "Octacarbonyldicobalt or cobalt(II) salts in the presence of a reducing agent and when modified with (R)-(6,6′-dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine) (MeO-BIPHEP) are active and highly enantioselective (ee up to 91.5%) catalyst precursors for the cyclocarbonylation of enynes such as 4,4-bis(carboethoxy)hex-6-en-1-yne. The reactivity of both catalytic systems towards cyclocarbonylation increases when the carbon monoxide pressure is increased. However, the enantioselectivity of the systems decreases, but increases again as the ligand-to-cobalt molar ratio increases." @default.
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- W2022489938 date "2004-07-01" @default.
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- W2022489938 title "Asymmetric cyclocarbonylation of 1,6-enynes with cobalt catalysts" @default.
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- W2022489938 doi "https://doi.org/10.1016/j.tetasy.2004.04.042" @default.
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