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- W2022492912 abstract "Abstract The effect of dissolved oxygen on the proton resonance lineshape and second moment of tetrahydrofuran deuteriohydrate between 4.5 and 260 K is interpreted in terms of the magnetic fields of the electron spins of reorienting oxygen molecules located in nearest-neighbor cages. After sufficient equilibration time, spin-lattice relaxation in the presence of oxygen becomes exponential at temperatures between 50 and 250 K with T 1 almost independent of temperature. Examples are cited of clathrate hydrate studies in which lineshapes and relaxation were affected by the presence of oxygen. Because of its large solubility in clathrate hydrates (∼ 0.7 mol/liter · atm in structure II ), particular care is required to exclude oxygen." @default.
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- W2022492912 date "1980-03-01" @default.
- W2022492912 modified "2023-09-29" @default.
- W2022492912 title "NMR behavior of the clathrate hydrate of tetrahydrofuran. III. Effect of oxygen" @default.
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- W2022492912 doi "https://doi.org/10.1016/0022-2364(80)90333-9" @default.
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