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• W2022503524 abstract "Atropisomerism is one of the basic concepts in stereochemistry. Chiral crystals of stereochemically labile atropisomers that originated from Mirror Symmetry Breaking (MSB) can only be characterized by solid-state chiroptical techniques. Herein, solid-state circular dichroism and UV-Vis spectra of six atropisomeric compounds (most of them were obtained from MSB) have been studied. A concentration effect including a wavelength shift and inverse concentration-dependence has been found and preliminarily explained by the absorption flattening effect, scattering effect and the torsion in the molecular structures." @default.
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• W2022503524 date "2011-01-01" @default.
• W2022503524 modified "2023-10-14" @default.
• W2022503524 title "Concentration effects in solid-state CD spectra of chiral atropisomeric compounds" @default.
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• W2022503524 doi "https://doi.org/10.1039/c1nj20185a" @default.
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