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- W2022504575 abstract "Two novel fullerene derivatives (μ-C60)Mo2(CO)6(η5-C5H4CO2Et)2 (1) and (μ-C60)W2(CO)6(η5-C5H4CO2Me)2 (2) were isolated from reactions of a tetrahydrofuran (THF) solution of dianion C602-, derived from C60 and potassium as well as α-methylnaphthalene, in situ with (η5-C5H4CO2Et)Mo(CO)3Cl and (η5-C5H4CO2Me)W(CO)3Cl, respectively (Scheme 1). The new complexes, in which the organometallic groups are attached at the 1,4-positions of C60 via assigned Mo−C(C60) σ-bonds, were characterized by elemental analysis and spectroscopic methods." @default.
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- W2022504575 date "1999-11-06" @default.
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- W2022504575 title "Synthesis and Isolation of σ-Bonded Fullerene Metal Derivatives from Reactions of Fullerene Dianion C<sub>60</sub><sup>2</sup><sup>-</sup> with Organometal Halides" @default.
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- W2022504575 doi "https://doi.org/10.1021/ol990088p" @default.
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