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• W2022504913 abstract "The electrical, magnetic and structural properties of synthetic chalcopyrite, CuFeS2, have been studied up to 873 K using DC resistance measurements performed in-situ during neutron powder diffraction experiments. Under ambient conditions the material adopts the accepted structural model for CuFeS2 in the space group I4̄2d, with the magnetic moment of the Fe3+ cations aligned along [001]. The electrical resistivity is around 0.3 Ω cm under ambient conditions, consistent with semiconductor character, and decreases slightly with increase in temperature until a more abrupt fall occurs in the region 750–800 K. This abrupt change in resistivity is accompanied by a structural transition to a cubic zinc blende structured phase (space group F4̄3m) in which Cu+ and Fe3+ cations are disordered over the same tetrahedral crystallographic sites and by a simultaneous loss of long-range magnetic order. The implications of these results are discussed in the context of previous studies of the chalcopyrite system." @default.
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• W2022504913 date "2011-08-01" @default.
• W2022504913 modified "2023-09-27" @default.
• W2022504913 title "A high temperature diffraction-resistance study of chalcopyrite, CuFeS2" @default.
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• W2022504913 doi "https://doi.org/10.1016/j.jssc.2011.06.036" @default.
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