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- W2022509168 abstract "Unter fast vollständigem Chiralitätstransfer verläuft die nucleophile Addition verschiedener Kohlenstoff- und Stickstoffnucleophile an das hoch enantiomerenangereicherte, planar chirale, 1-Phenylsulfonyl-substituierte (η3-Allyl)tetracarbonyl-eisen(1+)-tetrafluoroborat 1 (de,ee η 98%). Nach oxidativer Dekomplexierung eröffnet sich damit ein Zugang zu 3- substituierten Alkenylphenylsulfonen 2 hoher Enantiomerenreinheit (ee ⩾ 96%). Nu = C- oder N-Nucleophil." @default.
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- W2022509168 title "Eisen-unterstützte, regio- und stereoselektive allylische Substitutionen zu 3-substituierten Alkenylsulfonen" @default.
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