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- W2022553089 abstract "We present results of Raman and infrared spectroscopic studies of the composite system of superconducting YBa 2 Cu 3 O 7−δ and metallic BaPbO 3 , with the BaPbO 3 fraction ranging from 5 to 30 in weight. The Raman spectra of the YBa 2 Cu 3 O 7−δ grains in the composite system are typical of well-oxygenated YBa 2 Cu 3 O 7−δ bulk single crystals, even up to the grain boundaries, independent of the BaPbO 3 fraction. We have also performed infrared reflectivity measurements and have identified the major c -axis transverse-optical phonons of YBa 2 Cu 3 O 7−δ , consistent with the single-crystal data, confirming that the constituent YBa 2 Cu 3 O 7−δ crystallites are fully oxygenated. The absence of mode splitting suggests that the crystal symmetry of YBa 2 Cu 3 O 7−δ grains remains the same as that of bulk single crystals. No phonons indicative of other YBa 2 Cu 3 O 7 - or BaPbO 3 -related impurity phases, such as YBa 2 Cu 3 O 6 , Y 2 BaCuO 5 , and Ba 2 PbO 4 , have been detected in our Raman and infrared spectra. All these optical features clearly indicate that YBa 2 Cu 3 O 7−δ is well separated from BaPbO 3 and that BaPbO 3 is an excellent additive material for the synthesis of YBa 2 Cu 3 O 7−δ bulk materials." @default.
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- W2022553089 date "1998-11-01" @default.
- W2022553089 modified "2023-10-16" @default.
- W2022553089 title "Raman and infrared spectroscopy of YBa2Cu3O7−δ–BaPbO3 composites" @default.
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- W2022553089 doi "https://doi.org/10.1016/s0921-4534(98)00398-0" @default.
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