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- W2022577297 abstract "Tracer-diffusion of Co 2+ ions is studied in agar gel medium containing some alkaline earth metal chlorides and transition metal sulphates using the zone-diffusion technique. Verification of Onsager's theory for the diffusion in BaCl 2 and MnSO 4 shows a divergence between the experimental and theoretical values of diffusion coefficients which is attributed to the presence of gel as well as to diffusion enhancing interactions occurring in the solution state. The study of effect of supporting electrolyte on the obstruction effect shows that it decreases with increasing charge density of cation of the supporting electrolyte and is explained on the basis of competitive hydration between ions and agar macromolecules. The activation energy for the diffusion of cobalt ions in NiSO 4 and CaCl 2 is also reported and is found to be 16.6 ± 0.8 and 11.3 ± 0.5 kJ mol −1 , respectively." @default.
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- W2022577297 date "1986-01-01" @default.
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- W2022577297 title "Tracer-diffusion of Co2+ ions in some alkaline earth metal chlorides and transition metal sulphates" @default.
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- W2022577297 doi "https://doi.org/10.1016/0883-2889(86)90063-8" @default.
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