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• W2022603384 abstract "Binding interactions of a newly developed drug molecule namely 3,3′-bis(indolyl)-4-chlorophenylmethane (BICPM) with α-cyclodextrin have been studied using steady state and picosecond time resolved fluorometric techniques. A significant increase both in steady state anisotropy (r) and in the average rotational correlation time in the CD environments compared with that in a pure aqueous phase indicates that the rotational dynamics of BICPM are substantially slowed down upon binding with the α-cyclodextrin. Critical spectral analysis reveals the formation of two types of inclusion complex between the fluorophore and α-cyclodextrin (α-CD) depending on the relative population of the two. The stoichiometries and association constants of these complexes have been determined by monitoring the fluorescence data. Hydrodynamic radii of the formed 1 : 2 probe-α-cyclodextrin supramolecular complex have also been determined. From the determined hydrodynamic radii and from molecular docking analysis it is argued that probably two CD cavity shields the indole moiety in a face-to-face manner." @default.
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• W2022603384 date "2014-08-07" @default.
• W2022603384 modified "2023-09-23" @default.
• W2022603384 title "Binding interaction of a newly developed bisindole drug molecule with α-cyclodextrin: face to face shielding of indole hoops" @default.
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• W2022603384 doi "https://doi.org/10.1039/c4ra06087c" @default.
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