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- W2022604212 abstract "Five isomorphous d 0 transition metal oxofluoride compounds A 3 [ M 2 O x F 11 − x ]·( A F) 0.333 ( A = K, Rb, NH 4 ; M = Nb, Mo, W; x = 2, 4) have been synthesized from acid fluoride solutions, and their crystal structures have been determined by single-crystal X-ray diffraction. The basic structural building units are dinuclear M 2 X 11 (dimers) formed from NbOF 5 or Mo(W)O 2 F 4 octahedra connected by the fluorine bridging atom. In the Nb 2 O 2 F 9 dimer, the O atoms occupy apical corners. In the M 2 O 4 F 7 ( M = Mo, W) dimers two O atoms are also apically placed, whereas the other two O atoms are statistically disordered in equatorial planes. The arrangement of dimers is so that the hexagonal tunnels containing `free' fluoride ions are formed. During the irradiation process the orthorhombic structure of K 3 Nb 2 O 2 F 9 ·(KF) 0.333 transforms into a pseudo-trigonal one with a = 23.15 Å, which is the [101] diagonal of the orthorhombic unit cell. The other four trigonal crystals are merohedral twins." @default.
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- W2022604212 date "2012-11-16" @default.
- W2022604212 modified "2023-10-16" @default.
- W2022604212 title "Dinuclear oxofluorometallates as a new structural type of <i>d</i> <sup>0</sup> transition metal oxofluoride compound" @default.
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- W2022604212 doi "https://doi.org/10.1107/s0108768112042577" @default.
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