Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022608472> ?p ?o ?g. }
Showing items 1 to 80 of
80
with 100 items per page.
- W2022608472 abstract "Oxidation of methyl (phenylsulfonyl)dithioacetate (1) with m-chloroperbenzoic acid gave the sulfine C6H5SO2CH2C(SO)SCH3 (2).Deprotonation of 2 with TlOEt and subsequent S-alkylation of the thallium(I) salt with methyl iodide gave (phenylsulfonyl)ketene dimethyl dithioacetal moxonide (5). When other bases were used in the deprotonation step deoxygenated products, viz. C6H5SO2CHC(SCH3)2 were obtained. Evidence is presented that oxygen is lost by an intramolecular redox reaction of an initially formed vinylsulfenic ester.The new ketene dithioacetal monoxide 5 reacts with malonate anions in an additon-elimination reaction in which the phenylsulfonyl group serves as the leaving group." @default.
- W2022608472 created "2016-06-24" @default.
- W2022608472 creator A5073179210 @default.
- W2022608472 creator A5089960075 @default.
- W2022608472 date "2010-09-02" @default.
- W2022608472 modified "2023-09-26" @default.
- W2022608472 title "Chemistry of sulfines. Part 32. Synthesis and reactions of (phenylsulfonyl)ketene dimethyl dithioacetal monoxide" @default.
- W2022608472 cites W2016180580 @default.
- W2022608472 cites W2055110263 @default.
- W2022608472 cites W2078656478 @default.
- W2022608472 cites W2086184957 @default.
- W2022608472 cites W2145683361 @default.
- W2022608472 cites W2333019906 @default.
- W2022608472 cites W2951369420 @default.
- W2022608472 cites W3021800886 @default.
- W2022608472 doi "https://doi.org/10.1002/recl.19760950903" @default.
- W2022608472 hasPublicationYear "2010" @default.
- W2022608472 type Work @default.
- W2022608472 sameAs 2022608472 @default.
- W2022608472 citedByCount "16" @default.
- W2022608472 crossrefType "journal-article" @default.
- W2022608472 hasAuthorship W2022608472A5073179210 @default.
- W2022608472 hasAuthorship W2022608472A5089960075 @default.
- W2022608472 hasConcept C118629725 @default.
- W2022608472 hasConcept C145148216 @default.
- W2022608472 hasConcept C146686406 @default.
- W2022608472 hasConcept C155647269 @default.
- W2022608472 hasConcept C161790260 @default.
- W2022608472 hasConcept C164361826 @default.
- W2022608472 hasConcept C178790620 @default.
- W2022608472 hasConcept C185592680 @default.
- W2022608472 hasConcept C2777842516 @default.
- W2022608472 hasConcept C2778806918 @default.
- W2022608472 hasConcept C2778870691 @default.
- W2022608472 hasConcept C2778874822 @default.
- W2022608472 hasConcept C2780073701 @default.
- W2022608472 hasConcept C512735826 @default.
- W2022608472 hasConcept C82894169 @default.
- W2022608472 hasConceptScore W2022608472C118629725 @default.
- W2022608472 hasConceptScore W2022608472C145148216 @default.
- W2022608472 hasConceptScore W2022608472C146686406 @default.
- W2022608472 hasConceptScore W2022608472C155647269 @default.
- W2022608472 hasConceptScore W2022608472C161790260 @default.
- W2022608472 hasConceptScore W2022608472C164361826 @default.
- W2022608472 hasConceptScore W2022608472C178790620 @default.
- W2022608472 hasConceptScore W2022608472C185592680 @default.
- W2022608472 hasConceptScore W2022608472C2777842516 @default.
- W2022608472 hasConceptScore W2022608472C2778806918 @default.
- W2022608472 hasConceptScore W2022608472C2778870691 @default.
- W2022608472 hasConceptScore W2022608472C2778874822 @default.
- W2022608472 hasConceptScore W2022608472C2780073701 @default.
- W2022608472 hasConceptScore W2022608472C512735826 @default.
- W2022608472 hasConceptScore W2022608472C82894169 @default.
- W2022608472 hasLocation W20226084721 @default.
- W2022608472 hasOpenAccess W2022608472 @default.
- W2022608472 hasPrimaryLocation W20226084721 @default.
- W2022608472 hasRelatedWork W1573945698 @default.
- W2022608472 hasRelatedWork W1972656003 @default.
- W2022608472 hasRelatedWork W1985843021 @default.
- W2022608472 hasRelatedWork W1986540469 @default.
- W2022608472 hasRelatedWork W1988331852 @default.
- W2022608472 hasRelatedWork W1997896694 @default.
- W2022608472 hasRelatedWork W2002057143 @default.
- W2022608472 hasRelatedWork W2011472275 @default.
- W2022608472 hasRelatedWork W2017335707 @default.
- W2022608472 hasRelatedWork W2025613042 @default.
- W2022608472 hasRelatedWork W2041207502 @default.
- W2022608472 hasRelatedWork W2042542226 @default.
- W2022608472 hasRelatedWork W2057880347 @default.
- W2022608472 hasRelatedWork W2060824226 @default.
- W2022608472 hasRelatedWork W2157453789 @default.
- W2022608472 hasRelatedWork W2321233740 @default.
- W2022608472 hasRelatedWork W2950885192 @default.
- W2022608472 hasRelatedWork W2951995917 @default.
- W2022608472 hasRelatedWork W2952074702 @default.
- W2022608472 hasRelatedWork W2047369135 @default.
- W2022608472 isParatext "false" @default.
- W2022608472 isRetracted "false" @default.
- W2022608472 magId "2022608472" @default.
- W2022608472 workType "article" @default.