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- W2022609788 abstract "The ruthenium(IV) bis(allyl) complex [{Ru(μ3 : μ3-C10H16)Cl(μ-Cl)}2] (1) reacts with pyrazene to give a binuclear complex, [{Ru(μ3 : μ3-C10H16)Cl2}2(μ-N2C4H4)] (2), which exists in two diastereomeric forms of Ci (meso) and C2 (rac) symmetries. The analogous reaction with 1,3,5-triazine yields a mixture of mono-, bi- and trinuclear complexes, [{Ru(μ3 : μ3-C10H16)Cl2}n(N3C3H3 [n = 1 (4), n = 2 (5), n = 3 (6), which interconvert with one another in chloroform solution at room temperature. Complexes 5 and 6 have been isolated and, like 2, 5 exists as two diastereoisomers. Complex 6, however, possesses four isomeric forms. The class I mixed-valence RuIV-RuII pyrazene-bridged complex [(Ru(μ3 : μ3-C10H16)Cl2(μ-N2C4H4)RuCl2(μ6-p-MeC6H4CHMe2)] 7b) is also reported. Pretreatment of 1 with Ag[BF4] in acetone generates mono- and dicationic solvate species which readily react with polypyridyl and related ligands to generate the chelate species [Ru(μ3 : μ3-C10H16)Cl(L-L)[BF4] [L-L = 2,2′-bipyridyl (11), L-L = 1,10-phenanthroline (12)] and [Ru(μ3 : μ3-C10H16)(terpy)][BF4]2 (13) (terpy = 2,2t' : 6′,2″-terpyridine). Complex 11 has been characterized by X-ray crystallography." @default.
- W2022609788 created "2016-06-24" @default.
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- W2022609788 date "1992-01-01" @default.
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- W2022609788 title "Mono-, bi- and trinuclear bis(allyl) complexes of ruthenium(IV) containing N-donor ligands" @default.
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- W2022609788 doi "https://doi.org/10.1016/s0277-5387(00)83629-3" @default.
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