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- W2022627315 abstract "The radiation chemistry of aqueous solutions (pH 1-9) of dithiothreitol (DTT) has been investigated by pulsed and steady-state techniques. From G(H2S) in N2- and N2O-saturated solutions it was concluded for pH 5–9 that the majority of the solvated electrons and 25–40% of the hydroxyl radicals reacted with DTT to form H2S. Oxidized dithiothreitol (DTT-ox) was the other major product observed for pH 5–9. However, DTT-ox was not formed when DTT solutions were irradiated at pH 1 and 2. When nitrate ions were added as an electron scavenger over the pH range 5–9, G(DTT-ox) was not affected; at pH 9.0 G(H2S) decreased slightly but at pH 5–6, G(H2S) was reduced to that arising from the reaction of the hydroxyl radical. The reaction of CO2- with DTT-ox was studied at pH 4.6 and pH 9.0. At pH 9.0 the G(DTT)=3.3−0.2 indicated a simple two electron reduction of DTT-ox while at pH 4.6 the G(DTT) >25 implied a chain reaction had occurred." @default.
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- W2022627315 title "The radiolysis of aqueous solutions containing dithiothreitol and oxidized dithiothreitol" @default.
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- W2022627315 doi "https://doi.org/10.1016/0146-5724(82)90131-5" @default.
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