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• W2022643123 abstract "Ab initio calculations of cross sections and rate constants for elastic scattering and Zeeman relaxation in collisions of $mathrm{NH}(X{}^{3}{ensuremath{Sigma}}^{ensuremath{-}})$ molecules with ${}^{3}mathrm{He}$ atoms in a magnetic field are presented and the mechanism for Zeeman transitions in ground-state ${}^{3}ensuremath{Sigma}$ molecules is established. The potential surface for He-NH interaction is obtained using all-electron coupled-cluster calculations with single, double, and noniterative triple excitations in a basis set augmented by bond functions. The ratio of the rates for elastic energy transfer and Zeeman relaxation in NH-${}^{3}mathrm{He}$ collisions exceeds ${10}^{5}$ at temperatures between $0.5$ and 1 K." @default.
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• W2022643123 date "2003-11-12" @default.
• W2022643123 modified "2023-10-03" @default.
• W2022643123 title "Low-temperature collisions of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi mathvariant=normal>NH</mml:mi><mml:mo>(</mml:mo><mml:mi>X</mml:mi><mml:mrow><mml:msup><mml:mrow><mml:mi /></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mrow><mml:msup><mml:mrow><mml:mi>Σ</mml:mi></mml:mrow><mml:mrow><mml:mi>−</mml:mi></mml:mrow></mml:msup></mml:mrow><mml:mo>)</mml:mo></mml:math>molecules with He atoms in a magnetic field: An<i>ab initio…" @default.
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• W2022643123 doi "https://doi.org/10.1103/physreva.68.051401" @default.
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