FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022643480> ?p ?o ?g. }

• W2022643480 abstract "Abstract The kinetics of reaction between a series of monosubstituted cobalt carbonyls Co(CO) 2 NOL (with L = Sb(C 6 H 5 ) 3 , As(C 6 H 5 ) 3 , P(C 6 H 5 ) 3 , P(OC 6 H 5 ) 3 , P(OCH 3 ) 3 , and P(−C 4 H 9 ) 3 ) and the same bidentate ligand 1,2-bis(diphenylphosphino)ethane, have been studied. In all cases the end product is the disubstituted chelate complex Co(CO)NOP(C 6 H 5 ) 2 CH 2 CH 2 P(C 6 H 5 ) 2 . For L = P(C 6 H 5 ) 3 and P(OCH 3 ) 3 there are formed to an appreciable extent, at relatively low ligand-to-complex conc. ratios, also the disubstituted complexes Co(CO)NOL 2 . There is good evidence that the associative reaction mechanism goes through a path involving a primary step of substrates ligand displacement, followed by chelation. Only for Co(CO) 2 NOP(OCH 3 ) 3 , a primary step of substrate ligand displacement, follow-ligand again followed by chelation, is competitive with the above one. The order of reactivity for primary ligand displacement is the following: Sb(C 6 H 5 ) 3 >CO> As(C 6 H 5 ) 3 >P(OC 6 H 5 ) 3 >P(C 6 H 5 ) 3 >P(n−C 4 H 9 ) 3 . It is interpreted on the basis of the varied basicity and polarizability of the substrate ligand, and in specific cases of their additional π-bonding ability. Steric factors do not seem to play a relevant role." @default.
• W2022643480 created "2016-06-24" @default.
• W2022643480 creator A5041537291 @default.
• W2022643480 creator A5091152918 @default.
• W2022643480 date "1968-03-01" @default.
• W2022643480 modified "2023-09-27" @default.
• W2022643480 title "Kinetics of disubstitution reactions of 1,2-bis(diphenylphosphino) ethane with monosubstituted derivatives of Co(CO)3NO" @default.
• W2022643480 cites W1991239996 @default.
• W2022643480 cites W2004038548 @default.
• W2022643480 cites W2044487033 @default.
• W2022643480 cites W2045072523 @default.
• W2022643480 cites W2050384421 @default.
• W2022643480 cites W2065007885 @default.
• W2022643480 cites W2086270406 @default.
• W2022643480 cites W2090048005 @default.
• W2022643480 cites W2128333990 @default.
• W2022643480 cites W2141070791 @default.
• W2022643480 cites W2314503700 @default.
• W2022643480 cites W2316902573 @default.
• W2022643480 cites W2319803271 @default.
• W2022643480 cites W2323133649 @default.
• W2022643480 cites W2334127872 @default.
• W2022643480 doi "https://doi.org/10.1016/s0020-1693(00)87036-x" @default.
• W2022643480 hasPublicationYear "1968" @default.
• W2022643480 type Work @default.
• W2022643480 sameAs 2022643480 @default.
• W2022643480 citedByCount "7" @default.
• W2022643480 crossrefType "journal-article" @default.
• W2022643480 hasAuthorship W2022643480A5041537291 @default.
• W2022643480 hasAuthorship W2022643480A5091152918 @default.
• W2022643480 hasConcept C111368507 @default.
• W2022643480 hasConcept C115624301 @default.
• W2022643480 hasConcept C116569031 @default.
• W2022643480 hasConcept C121332964 @default.
• W2022643480 hasConcept C127313418 @default.
• W2022643480 hasConcept C142724271 @default.
• W2022643480 hasConcept C148898269 @default.
• W2022643480 hasConcept C155647269 @default.
• W2022643480 hasConcept C161790260 @default.
• W2022643480 hasConcept C170493617 @default.
• W2022643480 hasConcept C178516000 @default.
• W2022643480 hasConcept C178790620 @default.
• W2022643480 hasConcept C179104552 @default.
• W2022643480 hasConcept C185592680 @default.
• W2022643480 hasConcept C197404232 @default.
• W2022643480 hasConcept C201194858 @default.
• W2022643480 hasConcept C204787440 @default.
• W2022643480 hasConcept C2776910235 @default.
• W2022643480 hasConcept C2777289219 @default.
• W2022643480 hasConcept C49152291 @default.
• W2022643480 hasConcept C55493867 @default.
• W2022643480 hasConcept C62520636 @default.
• W2022643480 hasConcept C71240020 @default.
• W2022643480 hasConcept C71924100 @default.
• W2022643480 hasConceptScore W2022643480C111368507 @default.
• W2022643480 hasConceptScore W2022643480C115624301 @default.
• W2022643480 hasConceptScore W2022643480C116569031 @default.
• W2022643480 hasConceptScore W2022643480C121332964 @default.
• W2022643480 hasConceptScore W2022643480C127313418 @default.
• W2022643480 hasConceptScore W2022643480C142724271 @default.
• W2022643480 hasConceptScore W2022643480C148898269 @default.
• W2022643480 hasConceptScore W2022643480C155647269 @default.
• W2022643480 hasConceptScore W2022643480C161790260 @default.
• W2022643480 hasConceptScore W2022643480C170493617 @default.
• W2022643480 hasConceptScore W2022643480C178516000 @default.
• W2022643480 hasConceptScore W2022643480C178790620 @default.
• W2022643480 hasConceptScore W2022643480C179104552 @default.
• W2022643480 hasConceptScore W2022643480C185592680 @default.
• W2022643480 hasConceptScore W2022643480C197404232 @default.
• W2022643480 hasConceptScore W2022643480C201194858 @default.
• W2022643480 hasConceptScore W2022643480C204787440 @default.
• W2022643480 hasConceptScore W2022643480C2776910235 @default.
• W2022643480 hasConceptScore W2022643480C2777289219 @default.
• W2022643480 hasConceptScore W2022643480C49152291 @default.
• W2022643480 hasConceptScore W2022643480C55493867 @default.
• W2022643480 hasConceptScore W2022643480C62520636 @default.
• W2022643480 hasConceptScore W2022643480C71240020 @default.
• W2022643480 hasConceptScore W2022643480C71924100 @default.
• W2022643480 hasLocation W20226434801 @default.
• W2022643480 hasOpenAccess W2022643480 @default.
• W2022643480 hasPrimaryLocation W20226434801 @default.
• W2022643480 hasRelatedWork W1971344771 @default.
• W2022643480 hasRelatedWork W2007199299 @default.
• W2022643480 hasRelatedWork W2029996585 @default.
• W2022643480 hasRelatedWork W2032452726 @default.
• W2022643480 hasRelatedWork W2042491826 @default.
• W2022643480 hasRelatedWork W2042776278 @default.
• W2022643480 hasRelatedWork W2042971850 @default.
• W2022643480 hasRelatedWork W2043680268 @default.
• W2022643480 hasRelatedWork W2044487033 @default.
• W2022643480 hasRelatedWork W2044561030 @default.
• W2022643480 hasRelatedWork W2063953789 @default.
• W2022643480 hasRelatedWork W2078002429 @default.
• W2022643480 hasRelatedWork W2078250055 @default.
• W2022643480 hasRelatedWork W2085221651 @default.
• W2022643480 hasRelatedWork W2090048005 @default.
• W2022643480 hasRelatedWork W2103976139 @default.
• W2022643480 hasRelatedWork W2125483078 @default.
• W2022643480 hasRelatedWork W2152196709 @default.
• W2022643480 hasRelatedWork W2156998767 @default.

• next