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- W2022659350 abstract "We have calorimetrically measured the heat of reaction of vapour deposited calcium atoms on a poly[2-methoxy,5-(2′-ethylhexyloxy)-p-phenylene-vinylene] (MEH-PPV) substrate. We find that Ca has an initial heat of reaction of 360 kJ/mol, and that the reaction heat decreases rapidly with coverage. In contrast, on poly[2-methoxy,5-(2′-ethylhexyloxy)-p-phenylene], which lacks the vinylene group, we find the calcium has an initial reaction heat of only 200 kJ/mol, and that the reaction heat initially rises with coverage. We conclude that the vinylene group is the dominant reaction site for calcium on MEH-PPV." @default.
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- W2022659350 date "2004-02-01" @default.
- W2022659350 modified "2023-09-26" @default.
- W2022659350 title "A calorimetric study of the heat of reaction of calcium atoms with the vinylene group of MEH-PPV" @default.
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- W2022659350 doi "https://doi.org/10.1016/j.cplett.2003.12.055" @default.
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