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• W2022668772 abstract "Abstract Reactions of freshly precipitated MnCO3·xH2O and ZnCO3·yH2O with phen and fumaric acid (H2L) in EtOH/H2O afforded [Mn(phen)2(H2O)2]L·4H2O 1, Mn(phen)(H2O)2L 2 and Zn(phen)L·H2L 3, respectively. Compound 1 consists of [Mn(phen)2(H2O)2]2+ complex cations, fumarate anions and crystal H2O molecules. The complex cations are assembled by intermolecular π–π stacking interactions into 2D layers, between which the fumarate anions and crystal H2O molecules form hydrogen bonded 2D open network. Within the complex 2, the [Mn(phen)(H2O)2]2+ moieties are bridged by bis–monodentate fumarato ligands to generate 1D zigzag chains, which are assembled into 2D layers by weak C–H⋯O hydrogen bonds. The complex 3 is composed of fumaric molecules and 1D zigzag ∞ 1 [ Zn(phen)L 2 / 2 ] polymeric chains resulting from the [Zn(phen)]2+ moieties interlinked by bis–monodentate fumarato ligands. The polymeric chains and fumaric molecules are held together via significant π–π stacking interactions between the fumaric plane and pendant phen to form 2D layers, which are further assembled by interlayer O–H⋯O hydrogen bonds between hydroxyl group and non-coordinating fumarato O atom." @default.
• W2022668772 created "2016-06-24" @default.
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• W2022668772 date "2003-02-01" @default.
• W2022668772 modified "2023-10-17" @default.
• W2022668772 title "New catenary coordination polymers using fumarato ligand as bridging spacer: crystal structures of [Mn(phen)2(H2O)2]L·4H2O, Mn(phen)(H2O)2L and Zn(phen)L·H2L with H2L=fumaric acid" @default.
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• W2022668772 doi "https://doi.org/10.1016/s0022-2860(02)00615-4" @default.
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