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- W2022670023 abstract "Infrared spectra of polyethylene terephthalate and polyethylene-d4 terephthalate were investigated in the KBr and CsBr regions. No band attributable to a CO2 out-of-plane bending vibration was found below 700 cm−1. The only band assignable to this mode is a strong and perpendicular band at 727 cm−1. This fact together with the disappearance of the 727 cm−1 band in polyethylene deuteroterephthalate, indicates that two bands at 875 and 727 cm−1 in polyethylene terephthalate can be assigned to coupled vibrations of aromatic C–H and ester CO2 out-of-plane bending modes. This interpretation provides a consistent explanation for the spectral differences between ethylene glycol dibenzoate and 1,2-ethanedithiol dibenzoate and between ethylene glycol bis-(4-methoxycarbonylbenzoate) and 1,2-ethanedithiol bis-(4-methoxycarbonylbenzoate) as well as for the anomalous shifts of C–H out-of-plane frequencies and the appearances of “extra bands” in several aromatic esters." @default.
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- W2022670023 date "1960-07-01" @default.
- W2022670023 modified "2023-10-18" @default.
- W2022670023 title "On the Assignment of a Band at 727 cm−1in Polyethylene Terephthalate" @default.
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- W2022670023 doi "https://doi.org/10.1246/bcsj.33.992" @default.
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