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- W2022670092 abstract "The reaction between 3 eq MOCME3 (M = Na, K) and ZnCl2 in ethereal solvents affords the dimeric zincates M2[Zn(OCMe3)3]2 (1 M = Na, 2 M = K). The sodium derivative begins to sublime under vacuum at 50°C, and the potassium salt starts to sublime under vacuum at 90°C. Both zincates are soluble in hydrocarbon solvents. The X-ray crystal structures of both compounds were determined. The centrosymmetric structures consist of a (ZnOCMe3)2 ring with four terminal OCMe3 groups. An alkali metal ison is positioned above and below the Zn2O2 plane, each bonded to three oxygen atoms." @default.
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- W2022670092 date "1994-01-01" @default.
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- W2022670092 title "Synthesis and structure of tri-tert-butoxyzincates" @default.
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