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- W2022672395 abstract "The quantum yield Ø(eaq) of photoejected electrons from aromatic carboxylate anions in aqueous solutions (pH 9.5 – 12.3) appreciably increases with increasing excitation energy; for example, Ø(eaq) for benzoate is 0.0025 for the S1 state (excitation at 254 nm) and 0.0048 for the S2 state (excitation at 214 nm). The Ø(eaq) value also increases with the number of CH2 groups separating the phenyl and carboxylate groups; for example, for phenylbutyrate Ø(eaq) is 0.05 for the S1 state and 0.010 for the S2 state. Furthermore, increases of Ø(eaq) are linked with decreases in the quantum yield of fluorescence. In order to evaluate a possible consumption of the photoejected electrons by the ground state carboxylates, the rate constants k(eaq + substrate) for the reaction of solvated electrons with the corresponding substrates were determined." @default.
- W2022672395 created "2016-06-24" @default.
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- W2022672395 date "1985-03-01" @default.
- W2022672395 modified "2023-09-23" @default.
- W2022672395 title "Relationship between the quantum yields of electron photoejection and fluorescence of aromatic carboxylate anions in aqueous solution" @default.
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- W2022672395 doi "https://doi.org/10.1016/0047-2670(85)85040-1" @default.
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