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• W2022673565 abstract "A series of α′-aryl-α′-carbomethoxycycloalk-2-en-1-ones, 16, has been prepared using the Pinhey arylation methodology for introducing the aromatic residue. Subjection of these compounds to Johnson iodination and Pd[0]-catalyzed Ullmann cross-coupling of the resulting α-iodocycloalkenones 11 with 2-iodonitrobenzene (5, X = I) then affords α,α′-diaryl-α′-carbomethoxycycloalk-2-en-1-ones of the general form 10. Reductive cyclization of this last type of compound gives the corresponding indoles 9a–f (n = 1–3), some of which resemble the indole–indoline cores of the clinically important alkaloids (+)-vinblastine (1) and (+)-vincristine (2)." @default.
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• W2022673565 date "2008-08-01" @default.
• W2022673565 modified "2023-10-16" @default.
• W2022673565 title "The synthesis of compounds related to the indole–indoline core of the vinca alkaloids (+)-vinblastine and (+)-vincristine" @default.
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• W2022673565 doi "https://doi.org/10.1016/j.tetlet.2008.05.082" @default.
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