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- W2022673958 abstract "The specific rotation of β-d-fructofuranose in aqueous solution is positive (+78°) and that of methyl β-d-fructofuranoside is negative (−60°). The opposing chir-optical properties of these compounds are attributed to the formation by the former, of a hydrogen bond between the anomeric (OH—2) and C—6 hydroxyl groups to form a bicyclic and dextrorotatory chelate structure. The assignment explains the optical rotatory behaviour of d-fructose in aqueous solution at different temperatures and in aqueous alcohol, urea and borate solutions. It also explains precisely why β-d-fructofuranose is devoid of sweetness." @default.
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- W2022673958 date "1980-07-01" @default.
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- W2022673958 title "The structure of β-d-fructofuranose in aqueous solution" @default.
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- W2022673958 doi "https://doi.org/10.1016/0308-8146(80)90012-6" @default.
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