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- W2022676758 abstract "The compounds [TpReO(η2-N−X)] (X = N, O; Tp = hydrotrispyrazolylborate) were prepared from TpReOCl2 and chiral, bidentate ligands in which η2-N−X = the alcoholates or amidates derived from (1S,2R)-ephedrine, (1S,2S)-diphenylethylenediamine, and l-proline. The three complexes have been fully characterized by 1H NMR, IR, circular-dichroism, elemental analysis, polarimetry, and X-ray crystallography. All have a chiral center at rhenium. The complexes derived from (1S,2R)-ephedrine and l-proline were formed diastereoselectively as a single diastereomer. All of the complexes exhibited similar Re−O bond distances, ranging from 1.687(7) to 1.707(7) Å, consistent with distances found in other Re(V) oxo complexes. The electronic asymmetry at the metal caused by the different donor properties of the ligands leads to tilting of the Re−oxo bond relative to the plane of the equatorial ligands. The compounds were found to be robust and resisted oxo transfer even when subjected to harsh conditions." @default.
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- W2022676758 date "2000-08-23" @default.
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- W2022676758 title "Diastereoselective Synthesis and Electronic Asymmetry of Chiral Nonracemic Rhenium(V) Oxo Complexes Containing the Hydrotris(1-pyrazolyl)borate Ligand" @default.
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- W2022676758 doi "https://doi.org/10.1021/om000361n" @default.
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