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- W2022678818 abstract "Twelve Pr3+, Sm3+, Eu3+, Gd3+, Tb3+ and Dy3+ complexes of N-(pyridin-2-ylmethylene)picolinohydrazonate (phzp−) were synthesized by the Ln3+ assisted hydrolysis of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine. Crystallographic characterization of Pr3+, Sm3+ and Eu3+ hydrazonate complexes with nitrate or trifluoroacetyleacetonate co-ligands shows them to have binuclear structures with a planar Ln2O2 core and the ligand to be in its mono-anionic form. Exception is the Pr3+ complex with nitrate co-ligand, which is a mononuclear species containing the neutral hydrazone. Paramagnetic 1D 1H and 2D gCOSY and gNOESY–gEXSY 1H NMR spectroscopies revealed the presence of different isomers exhibiting a sterically controlled fluxional behavior. In addition, phzp− significantly enhances the luminescence of Eu3+ and Tb3+. Magnetic measurements show antiferromagnetic coupling between the Ln3+ ions in the dinuclear complexes. The structural characterization of the complexes in both solid state and solution show the versatility of phzp− ligand to adopt various ligating motifs." @default.
- W2022678818 created "2016-06-24" @default.
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- W2022678818 date "2013-11-01" @default.
- W2022678818 modified "2023-09-27" @default.
- W2022678818 title "Structure, reactivity, luminescence and magnetism of dinuclear Ln3+ complexes produced by the Ln3+-assisted hydrolysis of 3,6-bis(2-pyridyl)tetrazine" @default.
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- W2022678818 doi "https://doi.org/10.1016/j.poly.2013.05.037" @default.
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