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• W2022679967 abstract "Oxygen is the only elemental molecule which carries an electronic magnetic moment. As a consequence, the different solid phases encountered on cooling show various degrees of magnetic order, and similar behavior is expected under compression. Here we present neutron diffraction data which reveal the magnetic ordering under high pressure in the $ensuremath{delta}$ (``orange'') phase, i.e., in the range 6--8 GPa and 20--240 K. We show that $ensuremath{delta}mathrm{text{ensuremath{-}}}{mathrm{O}}_{2}$ contains in total three different magnetic structures, all of them being antiferromagnetic and differing in the stacking sequence of ${mathrm{O}}_{2}$ sheets along the $c$ axis. This structural diversity can be explained by the quasi-two-dimensional nature of $ensuremath{delta}mathrm{text{ensuremath{-}}}{mathrm{O}}_{2}$ and the strong orientation dependence of the magnetic exchange interaction between ${mathrm{O}}_{2}$ molecules. The results show that $ensuremath{delta}mathrm{text{ensuremath{-}}}{mathrm{O}}_{2}$ is a room temperature antiferromagnet." @default.
• W2022679967 created "2016-06-24" @default.
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• W2022679967 date "2010-03-16" @default.
• W2022679967 modified "2023-10-18" @default.
• W2022679967 title "Magnetic Ordering in Solid Oxygen up to Room Temperature" @default.
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• W2022679967 doi "https://doi.org/10.1103/physrevlett.104.115501" @default.
• W2022679967 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20366482" @default.
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