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- W2022685208 abstract "Making Ns meet: Triphenylphosphinazine N2(PPh3)2 is a donor–acceptor complex between nitrogen in the highly excited 1Γg state and two anti-periplanar coordinated phosphine ligands (see structure). Although the dissociation into N2+2 PPh3 is calculated to be exergonic by 75 kcal mol−1, the compound is kinetically very stable as a result of the very large Lewis acidity of N2 in the excited 1Γg state." @default.
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- W2022685208 date "2013-02-04" @default.
- W2022685208 modified "2023-10-11" @default.
- W2022685208 title "Dinitrogen as Double Lewis Acid: Structure and Bonding of Triphenylphosphinazine N<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>" @default.
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- W2022685208 doi "https://doi.org/10.1002/anie.201206305" @default.
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