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- W2022687237 abstract "Picosecond infrared saturation-recovery experiments were performed to obtain measurements of the vibrational energy lifetimes (T1) of CO(v = 1) vibrations (v≈ 1920-1985 cm−1) of carbonyl-containing metal complexes in dilute, room-temperature solutions. For relaxation of the F1u CO-stretching vibration of W(CO)6 in CCl4, CHCl3, n-hexane and benzene, T1, was found to be T1 = 800±200, 480±50, 140±15 and 60±6 ps, respectively, while the same mode of Cr(CO)6, in these solvents gave T1 = 440±70, 295±30, 145±25 and 59±6 ps. Monocarbonyl complexes with coordinated triphenylphosphine groups (TPP) have shorter CO(v = 1 ) lifetimes. These observations are rationalized in terms of molecular structure, intramolecular bonding, solvent interaction, and energy accepting vibrational modes." @default.
- W2022687237 created "2016-06-24" @default.
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- W2022687237 date "1987-02-01" @default.
- W2022687237 modified "2023-10-18" @default.
- W2022687237 title "Population relaxation of CO(v = 1 ) vibrations in solution phase metal carbonyl complexes" @default.
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- W2022687237 doi "https://doi.org/10.1016/0009-2614(87)87118-x" @default.
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