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• W2022687756 abstract "The reorientation of dye molecules can be used to monitor the segmental dynamics of a polymer melt. We utilize this technique to measure stress-induced mobility in a lightly cross-linked poly(methyl methacrylate) (PMMA) glass during tensile creep deformation. At 377K (18K below the glass transition temperature Tg), the mobility increased by a factor of 100 during deformation with a stress of 20MPa. Generally, the mobility increased as the stress, strain, and strain rate increased. After removing the stress, we observed that the enhanced mobility slowly disappeared during strain recovery. At 377K, when the stress is lower than 11MPa, almost no mobility enhancement was observed. Once the stress crossed this threshold value, the mobility dramatically increased." @default.
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• W2022687756 date "2008-04-03" @default.
• W2022687756 modified "2023-09-27" @default.
• W2022687756 title "Dye reorientation as a probe of stress-induced mobility in polymer glasses" @default.
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• W2022687756 doi "https://doi.org/10.1063/1.2868774" @default.
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