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• W2022690261 abstract "The synthesis and characterization of the previously unknown SiW9(NbO2)3O377−, a novel composition of matter containing three adjacent NbvO2 peroxide groups, is described. Also reported is a survey of the catalytic epoxidation of seven olefinic substrates with 30% aqueous H2O2 using this heteropolyanion as a precatalyst. Additionally, the preliminary kinetic evidence presented indicates that SiW9(NbO2)3O377− serves as a catalyst precursor to the true catalyst, a catalytically active W, Nb or polyoxoanion fragment." @default.
• W2022690261 created "2016-06-24" @default.
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• W2022690261 date "1991-11-01" @default.
• W2022690261 modified "2023-09-27" @default.
• W2022690261 title "A novel triperoxyniobium-containing polyoxoanion, SiW9(NbO2)3O377−: synthesis, characterization, catalytic allylic epoxidations with H2O2 and preliminary kinetic studies" @default.
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• W2022690261 doi "https://doi.org/10.1016/0304-5102(91)80113-h" @default.
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