Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022690295> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2022690295 endingPage "163" @default.
- W2022690295 startingPage "151" @default.
- W2022690295 abstract "Abstract The coadsorption of methanol and oxygen on Cu(100) has been examined using secondary ion mass spectrometry (SIMS). The study provides a mass-spectrometric observation of the surface intermediates present during adsorption at 130 K, and after heating to 320 K. Isotopically-labelled reagents ( 18 O 2 , CD3OD, CH3OD) have been used to facilitate the interpretation of spectra. The SIMS data indicate that MeOD dissociates at 130 K in the presence of pre-adsorbed 18 O 2 to yield a physisorbed D2O layer, in addition to a methoxy (MeO) intermediate and other products. Spectra obtained at 320 K reveal an enhanced concentration of formate species (predominantly as HC 18 O 16 O ). The principal positive secondary ion associated with the methoxy intermediate was found to be CuCH2O+, rather than the expected CuCH3O+, which was not detected. The observed behaviour is consistent with reaction mechanisms proposed by Wachs and Madix to account for methanol oxidation on O/Cu surfaces [J. Catal. 31 (1982) 243]." @default.
- W2022690295 created "2016-06-24" @default.
- W2022690295 creator A5054324974 @default.
- W2022690295 creator A5065249672 @default.
- W2022690295 date "2001-03-01" @default.
- W2022690295 modified "2023-10-18" @default.
- W2022690295 title "Characterisation of adsorbed intermediates in the CH3OH/O/Cu(100) system by secondary ion mass spectrometry" @default.
- W2022690295 cites W1506966363 @default.
- W2022690295 cites W1661576376 @default.
- W2022690295 cites W1964914777 @default.
- W2022690295 cites W1970848423 @default.
- W2022690295 cites W1972837656 @default.
- W2022690295 cites W1975378999 @default.
- W2022690295 cites W1981477263 @default.
- W2022690295 cites W1984655961 @default.
- W2022690295 cites W1995784497 @default.
- W2022690295 cites W1997311288 @default.
- W2022690295 cites W2002564347 @default.
- W2022690295 cites W2007205227 @default.
- W2022690295 cites W2022155584 @default.
- W2022690295 cites W2027942658 @default.
- W2022690295 cites W2029002738 @default.
- W2022690295 cites W2034805998 @default.
- W2022690295 cites W2035142413 @default.
- W2022690295 cites W2039672537 @default.
- W2022690295 cites W2042321451 @default.
- W2022690295 cites W2044502459 @default.
- W2022690295 cites W2046561577 @default.
- W2022690295 cites W2048886573 @default.
- W2022690295 cites W2056611491 @default.
- W2022690295 cites W2057361235 @default.
- W2022690295 cites W2059299592 @default.
- W2022690295 cites W2065894676 @default.
- W2022690295 cites W2067371137 @default.
- W2022690295 cites W2068944521 @default.
- W2022690295 cites W2083579701 @default.
- W2022690295 cites W2084816499 @default.
- W2022690295 cites W2085771597 @default.
- W2022690295 cites W2087447552 @default.
- W2022690295 cites W2090770913 @default.
- W2022690295 cites W2091300353 @default.
- W2022690295 cites W2092040884 @default.
- W2022690295 cites W2095408063 @default.
- W2022690295 cites W2324444405 @default.
- W2022690295 cites W2331184711 @default.
- W2022690295 cites W4232987078 @default.
- W2022690295 doi "https://doi.org/10.1016/s0169-4332(00)00901-6" @default.
- W2022690295 hasPublicationYear "2001" @default.
- W2022690295 type Work @default.
- W2022690295 sameAs 2022690295 @default.
- W2022690295 citedByCount "8" @default.
- W2022690295 crossrefType "journal-article" @default.
- W2022690295 hasAuthorship W2022690295A5054324974 @default.
- W2022690295 hasAuthorship W2022690295A5065249672 @default.
- W2022690295 hasConcept C113196181 @default.
- W2022690295 hasConcept C145148216 @default.
- W2022690295 hasConcept C147789679 @default.
- W2022690295 hasConcept C150394285 @default.
- W2022690295 hasConcept C162356407 @default.
- W2022690295 hasConcept C178790620 @default.
- W2022690295 hasConcept C185592680 @default.
- W2022690295 hasConcept C187529661 @default.
- W2022690295 hasConcept C43617362 @default.
- W2022690295 hasConcept C77671233 @default.
- W2022690295 hasConceptScore W2022690295C113196181 @default.
- W2022690295 hasConceptScore W2022690295C145148216 @default.
- W2022690295 hasConceptScore W2022690295C147789679 @default.
- W2022690295 hasConceptScore W2022690295C150394285 @default.
- W2022690295 hasConceptScore W2022690295C162356407 @default.
- W2022690295 hasConceptScore W2022690295C178790620 @default.
- W2022690295 hasConceptScore W2022690295C185592680 @default.
- W2022690295 hasConceptScore W2022690295C187529661 @default.
- W2022690295 hasConceptScore W2022690295C43617362 @default.
- W2022690295 hasConceptScore W2022690295C77671233 @default.
- W2022690295 hasIssue "1-2" @default.
- W2022690295 hasLocation W20226902951 @default.
- W2022690295 hasOpenAccess W2022690295 @default.
- W2022690295 hasPrimaryLocation W20226902951 @default.
- W2022690295 hasRelatedWork W1972063890 @default.
- W2022690295 hasRelatedWork W2003917734 @default.
- W2022690295 hasRelatedWork W2026642978 @default.
- W2022690295 hasRelatedWork W2037971214 @default.
- W2022690295 hasRelatedWork W2058013599 @default.
- W2022690295 hasRelatedWork W2084930536 @default.
- W2022690295 hasRelatedWork W2089465129 @default.
- W2022690295 hasRelatedWork W2153263373 @default.
- W2022690295 hasRelatedWork W2333789297 @default.
- W2022690295 hasRelatedWork W40586433 @default.
- W2022690295 hasVolume "173" @default.
- W2022690295 isParatext "false" @default.
- W2022690295 isRetracted "false" @default.
- W2022690295 magId "2022690295" @default.
- W2022690295 workType "article" @default.