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- W2022691208 abstract "The system olefin-NiO has been investigated by means of a thermodesorption technique. A decrease in the temperature of desorption, TmI > TmII > TmIII was observed following the first, second, and third introduction of olefin to the NiO catalyst (at a uniform rate of the temperature rise); on further introduction of the olefin, the catalyst is “stabilized” and Tm remains constant. The energy of activation of desorption and the heats of adsorption of some olefins have been determined. Reversible chemisorption of ethylene on NiO takes place on a surface estimated to amount to 0.08 – 0.15% of the total surface under the various experimental conditions used. The chromatograms recorded after the third and following introductions of olefin show a peak due to reversibly chemisorbed olefin and a group of peaks due to products of irreversible chemisorption (dimers, oxygen-containing compounds, etc.)." @default.
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- W2022691208 date "1971-09-01" @default.
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- W2022691208 title "A thermodesorption study of the system olefin-NiO" @default.
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- W2022691208 doi "https://doi.org/10.1016/0021-9517(71)90200-4" @default.
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