Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022698029> ?p ?o ?g. }
- W2022698029 endingPage "3805" @default.
- W2022698029 startingPage "3796" @default.
- W2022698029 abstract "The dicationic Ru(IV) salt [Ru(Cp*)(η3-C3H5)(CH3CN)2](PF6)2 is shown to be an excellent and rapid catalyst for the C-allylation of indole compounds using allyl alcohols as substrates. Selective, one-pot N,C-double allylation is also possible. Preliminary experiments suggest that vinyl epoxides may be used as an allyl source. Stoichiometric reactions of CH2═CHCH(OH)CH═CH2, CH2═CHCH(OAc)CH═CH2, and CH2═CHCH═CHCH2Br with [Ru(Cp*)(CH3CN)3](PF6) afford new Ru(IV) η3-vinyl-allyl salts, two of which, [Ru(Cp*)(κ2-OAc)(η3-vinyl-allyl)](PF6) (13) and [Ru(Cp*)Br(η3-vinyl-allyl)(CH3CN)](PF6) (14), have been studied by X-ray diffraction methods. In addition to the Ru(IV) η3-vinyl-allyl bonding mode, we also find an isomer of the bromo salt 14 possessing a dynamic Ru(IV) S (rather than U)-shaped η5-pentadienyl moiety, 20. DFT computational results for 20 indicate that the S-shaped rather than the U-shaped form is the most stable Ru(IV) species and that the stability difference between these two forms is mainly due to interligand repulsion between the Br and pentadienyl ligands." @default.
- W2022698029 created "2016-06-24" @default.
- W2022698029 creator A5011798688 @default.
- W2022698029 creator A5020406885 @default.
- W2022698029 creator A5037478989 @default.
- W2022698029 creator A5046772276 @default.
- W2022698029 creator A5048941488 @default.
- W2022698029 date "2008-07-17" @default.
- W2022698029 modified "2023-10-16" @default.
- W2022698029 title "Facile Ruthenium(IV)-Catalyzed Single and Double Allylation of Indole Compounds using Alcohols as Substrates: Aspects of Ruthenium(IV) Allyl Chemistry" @default.
- W2022698029 cites W123872719 @default.
- W2022698029 cites W1964837435 @default.
- W2022698029 cites W1967177376 @default.
- W2022698029 cites W1968895281 @default.
- W2022698029 cites W1971275758 @default.
- W2022698029 cites W1974636544 @default.
- W2022698029 cites W1975708211 @default.
- W2022698029 cites W1980404785 @default.
- W2022698029 cites W1981371341 @default.
- W2022698029 cites W1983506768 @default.
- W2022698029 cites W1984599229 @default.
- W2022698029 cites W1985023721 @default.
- W2022698029 cites W1990031849 @default.
- W2022698029 cites W1992804995 @default.
- W2022698029 cites W1993159104 @default.
- W2022698029 cites W1993383767 @default.
- W2022698029 cites W1995042715 @default.
- W2022698029 cites W1995377603 @default.
- W2022698029 cites W1995794402 @default.
- W2022698029 cites W1997151511 @default.
- W2022698029 cites W1998552049 @default.
- W2022698029 cites W2000089659 @default.
- W2022698029 cites W2001987125 @default.
- W2022698029 cites W2002324876 @default.
- W2022698029 cites W2004047988 @default.
- W2022698029 cites W2008483766 @default.
- W2022698029 cites W2011254772 @default.
- W2022698029 cites W2013360147 @default.
- W2022698029 cites W2013681136 @default.
- W2022698029 cites W2015516088 @default.
- W2022698029 cites W2018399161 @default.
- W2022698029 cites W2021339532 @default.
- W2022698029 cites W2023950805 @default.
- W2022698029 cites W2026228805 @default.
- W2022698029 cites W2028363635 @default.
- W2022698029 cites W2030206545 @default.
- W2022698029 cites W2030687437 @default.
- W2022698029 cites W2031125844 @default.
- W2022698029 cites W2031633580 @default.
- W2022698029 cites W2032054382 @default.
- W2022698029 cites W2032987324 @default.
- W2022698029 cites W2036174533 @default.
- W2022698029 cites W2037410354 @default.
- W2022698029 cites W2038083805 @default.
- W2022698029 cites W2038193875 @default.
- W2022698029 cites W2038767330 @default.
- W2022698029 cites W2039415596 @default.
- W2022698029 cites W2039668672 @default.
- W2022698029 cites W2041812621 @default.
- W2022698029 cites W2044490585 @default.
- W2022698029 cites W2044961513 @default.
- W2022698029 cites W2046412723 @default.
- W2022698029 cites W2047282411 @default.
- W2022698029 cites W2050571057 @default.
- W2022698029 cites W2050931844 @default.
- W2022698029 cites W2054704030 @default.
- W2022698029 cites W2055941125 @default.
- W2022698029 cites W2056674373 @default.
- W2022698029 cites W2058363175 @default.
- W2022698029 cites W2060458322 @default.
- W2022698029 cites W2064956848 @default.
- W2022698029 cites W2066292028 @default.
- W2022698029 cites W2066582147 @default.
- W2022698029 cites W2068617439 @default.
- W2022698029 cites W2074968729 @default.
- W2022698029 cites W2075381847 @default.
- W2022698029 cites W2075662351 @default.
- W2022698029 cites W2076912405 @default.
- W2022698029 cites W2079835265 @default.
- W2022698029 cites W2081940318 @default.
- W2022698029 cites W2082712943 @default.
- W2022698029 cites W2083693692 @default.
- W2022698029 cites W2085966856 @default.
- W2022698029 cites W2086288648 @default.
- W2022698029 cites W2086324115 @default.
- W2022698029 cites W2087330456 @default.
- W2022698029 cites W2089013659 @default.
- W2022698029 cites W2091599818 @default.
- W2022698029 cites W2094634961 @default.
- W2022698029 cites W2094642658 @default.
- W2022698029 cites W2101049266 @default.
- W2022698029 cites W2102473396 @default.
- W2022698029 cites W2106508600 @default.
- W2022698029 cites W2110671121 @default.
- W2022698029 cites W2113149303 @default.
- W2022698029 cites W2115697879 @default.
- W2022698029 cites W2116631721 @default.
- W2022698029 cites W2118835659 @default.