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• W2022698624 abstract "High-quality poly(N-(9-fluorenylmethoxycarbony)-glycine) (PFG), a new kind of soluble polyfluorene derivative, was successfully synthesized electrochemically by direct anodic oxidation of N-(9-fluorenylmethoxycarbony)-glycine (FG) in boron trifluoride diethyl etherate (BFEE). The onset oxidation potential of FG in BFEE was only 0.6 V vs. Pt, which was much lower than that in acetonitrile +0.1 mol/L tetrabutylammonium tetra?uoroborate (TBATFB). PFG film obtained from BFEE showed good electrochemical activity and thermal stability. It indicates that BFEE is a better medium for the electrosynthesis of PFG film. PFG is highly soluble in common organic solvents, facilitating potential applications as a blue-light-emitting material. Fluorescent spectra revealed that PFG was a good blue-light emitter. Results of FT-IR and 1H NMR spectra indicated the polymerization location of N-(9-fluorenylmethoxycarbony)-glycine occurred mainly at C(2) and C(7) positions of the fluorine ring." @default.
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• W2022698624 date "2012-02-29" @default.
• W2022698624 modified "2023-09-23" @default.
• W2022698624 title "Electrosynthesis and Characterization of Poly(N-(9-fluorenylmethoxycarbony)-glycine)" @default.
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• W2022698624 doi "https://doi.org/10.1002/cjoc.201100283" @default.
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