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- W2022702471 abstract "Abstract Unsolvated diphenylmagnesium is solubilized in aromatic hydrocarbon solvents by an alkali metal 2-ethoxyethoxide. The mode of interaction between Ph 2 Mg and MOCH 2 CH 2 OEt (M = Li, Na, K) varies with M. For M = Li the complex formed has an Mg/Li ratio equal to 1.3/1.0, and is evidently different from the PhLi/Mg(OCH 2 CH 2 OEt) 2 complex. For M = Na, the metal—metal interchange apparently leads to a complex identical to that derived from PhNa and Mg(OCH 2 CH 2 OEt). For M = K the results are not conclusive. The width of the resonance 13 C from the ipso -carbon, increases with increasing ionic radius, and for M = K the signal is too broad to be clearly observed. The ipso -carbon in the NMR spectrum of the PhNa/Mg(OCH 2 CH 2 OEt) complex has now been shown to give rise to resonance at 175.95 ppm. Metalation experiments involving Ph 2 Mg along with two equivalents of MOCH 2 CH 2 OEt indicated that reactivity increases in the order Li" @default.
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- W2022702471 date "1985-07-01" @default.
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- W2022702471 title "The diphenylmagnesium/alkali metal alkoxide system. Hydrocarbon-soluble organoalkali metal reagents" @default.
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- W2022702471 doi "https://doi.org/10.1016/0022-328x(85)80143-1" @default.
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