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• W2022704463 endingPage "13231" @default.
• W2022704463 startingPage "13231" @default.
• W2022704463 abstract "Hydrothermal reaction of a tripodal bridging ligand, 5-(4-carboxyphenoxy)isophthalic acid (H3cpia) with cobalt salts modulated by N-donor neutral ligands leads to the formation of six novel coordination networks formulated as {[Co(1.5)(cpia)(o-bix)](H2O)(1.5)}n (1), {[Co2(cpia)(μ-OH)(m-bix)]H2O}n (2), {[Co(1.5)(cpia)(m-bix)]}n (3), {[Co(1.5)(cpia)(p-bix)(0.5)(H2O)]H2O}n (4), {[Co(2.5)(cpia)(Hcpia)(4,4'-bpy)(2.5)](H2O)3}n (5), and {[Co3(cpia)2(bpp)2]H2O}n (6). Compound 1 exhibits a two-dimensional, (3,8)-connected layered architecture composed of trinuclear cobalt clusters. Compound 2 possesses a three-dimensional dense framework with (3,8)-connected tfz-d topology built from butterfly-shaped tetranuclear Co4(μ3-OH)2(6+) clusters. Similar to compound 1, trinuclear Co clusters act as secondary building units to construct the final 2D layered structure modulated by m-bix and bpp ligands in compounds 3 and 6. In compound 4, trinuclear Co clusters connected by cpia(3-) anions give rise to two-dimensional layers, which are further pillared by p-bix ligands to the three-dimensional framework. Compound 5 features a 2D, (3,4,6)-connected molecular network assembled from alternate binuclear and mononuclear Co building blocks. The magnetic investigation indicates that strong antiferromagnetic interactions between cobalt ions are dominant in compounds 2 and 6." @default.
• W2022704463 created "2016-06-24" @default.
• W2022704463 creator A5005245760 @default.
• W2022704463 creator A5013100135 @default.
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• W2022704463 creator A5054467532 @default.
• W2022704463 creator A5064911441 @default.
• W2022704463 creator A5082373596 @default.
• W2022704463 creator A5082517492 @default.
• W2022704463 date "2013-01-01" @default.
• W2022704463 modified "2023-09-23" @default.
• W2022704463 title "Employing tripodal carboxylate ligand to construct Co(ii) coordination networks modulated by N-donor ligands: syntheses, structures and magnetic properties" @default.
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• W2022704463 doi "https://doi.org/10.1039/c3dt51241j" @default.
• W2022704463 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23884539" @default.

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