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- W2022707164 abstract "Abstract In the present paper, the hydroformylation of a commercial polyisobutene promoted by the presence of a cobalt catalyst has been studied. Two types of double bonds with different structures and reactivities were recognized as predominant in the substrate, by analysis with NMR techniques. With the same technique, the evolution with time of the two mentioned double bounds to give the corresponding aldehyde and alcohol has been studied. We observed that the more hindered double bonds start to react when the chain terminal double bonds have almost completely reacted. This observation can be explained only by assuming highly different equilibrium constants for the formation of cobalt coordination complexes with the two types of olefins." @default.
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- W2022707164 title "Hydroformylation of polyisobutene" @default.
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- W2022707164 doi "https://doi.org/10.1016/0304-5102(91)80099-o" @default.
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