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• W2022708904 abstract "A previously untested essential consequence of the TICT (twisted internal charge transfer) interpretation of the nature of the anomalous excited state of p-dimethylaminobenzonitrile (1) and related compounds has now been verified: at -90 degreesC, the dual fluorescence of a desymmetrized analogue, 2-(N-methyl-N-isopropylamino)-5-cyanopyridine (2), in methanol (MeOH) is accompanied by syn-anti isomerization around the C-N bond, whereas its ordinary fluorescence in tetrahydrofuran is not." @default.
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• W2022708904 date "2002-02-21" @default.
• W2022708904 modified "2023-09-27" @default.
• W2022708904 title "An Experimental Test of C−N Bond Twisting in the TICT State: Syn−Anti Photoisomerization in 2-(<i>N</i>-Methyl-<i>N</i>-isopropylamino)-5-cyanopyridine" @default.
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• W2022708904 doi "https://doi.org/10.1021/ja012326t" @default.
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