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- W2022709035 abstract "Abstract The effects of heat treatments in a vacuum chamber for a single crystal of LiNbO 3 have been examined with XPS, CAICISS and NO adsorption as a model reaction. The single crystal of LiNbO 3 was reduced by heating at 400°C for 1 h in a vacuum chamber. The loss of lithium and the creation of oxygen vacancies and lower valence niobium ions (Nb 4+ ) were detected with XPS. The crystal structure of the topmost layer of the heated sample was detected as LiNbO 3 in good order with CAICISS. Heating seems to order the topmost layer, and refill the vacancies by diffusion of oxygen and lithium through the surface. NO adsorbed as NO 2 and NO 3 on this ordered layer of LiNbO 3 ." @default.
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- W2022709035 date "1997-11-01" @default.
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- W2022709035 title "The effects of heat treatments upon NO adsorption for a single crystal of LiNbO3" @default.
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- W2022709035 doi "https://doi.org/10.1016/s0169-4332(97)00340-1" @default.
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