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• W2022718532 abstract "A highly stereoselective synthesis of the C1–C14 macrolactone core of the cytotoxic macrolide (–)-callipeltoside A has been achieved by utilizing an anti-selective aldol reaction and Wittig olefination to introduce an (E)-trisubstituted alkene, chemoselective diisobutylaluminum hydride (DIBAL-H) reduction of the 2,3-epoxy tosylate to install the C13 stereocenter, and intramolecular trapping of the acyl-ketene intermediate by the C13 hydroxy group as key steps." @default.
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• W2022718532 date "2012-02-10" @default.
• W2022718532 modified "2023-10-18" @default.
• W2022718532 title "Towards the Synthesis of (-)-Callipeltoside A: Stereoselective Synthesis of the C1-C14 Macrolactone Core" @default.
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• W2022718532 doi "https://doi.org/10.1002/ejoc.201101635" @default.
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