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- W2022721887 abstract "The standard enthalpies of formation for some 4d transition metal silicides have been measured by high temperature direct synthesis calorimetry at 1473±2 K. The following results in kJ (mole of atoms)−1 are reported: Y5Si3 (−80.4±2.3); YSi (−80.7±1.3); YSi2 (−61.8±1.4); Zr5Si4 (−91.9±1.9); ZrSi (−94.5±2.3); ZrSi2 (−60.3±1.7); Nb5Si3 (−64.6±2.4); NbSi2 (−53.7±1.6); Mo5Si3 (−38.2±1.6); MoSi2 (−47.9±2.1); RuSi (−58.1±2.1); Ru2Si3 (−60.7±1.7); Rh2Si (−63.9±2.4); RhSi (−75.8±1.6); Pd3Si (−57.9±1.9) and Pd2Si (−64.2±2.4). The results are compared with some earlier values obtained by calorimetry or derived from EMF or vapor pressure measurements. They are also compared with predicted values from the semi-empirical model of Miedema and coworkers and with available enthalpies of formation for 3d transition metal silicides, and with values for 4d germanides and aluminides." @default.
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- W2022721887 date "1998-06-01" @default.
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- W2022721887 title "Standard enthalpies of formation of some 4d transition metal silicides by high temperature direct synthesis calorimetry" @default.
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- W2022721887 doi "https://doi.org/10.1016/s0925-8388(98)00504-0" @default.
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