Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022721892> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2022721892 endingPage "2335" @default.
- W2022721892 startingPage "2325" @default.
- W2022721892 abstract "Homogeneous nucleation rates J in supersaturated n-alcohol vapors (methanol through n-hexanol) were measured in a two-piston expansion chamber as functions of supersaturation S and temperature T. The measured nucleation rates were compared with the classical nucleation theory. We found that the slopes of the J–S curves are in good agreement with the theoretical prediction. However, the actual values of experimental and theoretical rates were generally found to differ significantly, Jexptl/Jtheor ranging from about 10−10 (methanol, 273 K) to 107 (n-hexanol, 257 K). In particular, the experimental nucleation rates show a significantly weaker temperature dependence as compared to the classical nucleation theory, the difference being more pronounced for the higher alcohols. Thus, a temperature dependent correction to the classical nucleation theory is needed. For the lower alcohols, in particular methanol, we found that the change of the cluster distribution during the expansion strongly influences the nucleation process. The heat released during the formation of oligomers causes a significant temperature increase in the system and thus alters the nucleation conditions dramatically. For methanol vapor under the considered experimental conditions this effect leads to a reduction of the theoretically predicted nucleation rates by factors up to about 108. Since oligomer formation is prerequisite to nucleation, this effect has to be taken into account generally for nucleation experiments in adiabatically closed systems." @default.
- W2022721892 created "2016-06-24" @default.
- W2022721892 creator A5040451729 @default.
- W2022721892 creator A5044408891 @default.
- W2022721892 creator A5049991586 @default.
- W2022721892 date "1986-02-15" @default.
- W2022721892 modified "2023-09-27" @default.
- W2022721892 title "Homogeneous nucleation rates for<i>n</i>‐alcohol vapors measured in a two‐piston expansion chamber" @default.
- W2022721892 cites W1974498102 @default.
- W2022721892 cites W1986661117 @default.
- W2022721892 cites W1987393406 @default.
- W2022721892 cites W1990682288 @default.
- W2022721892 cites W1991916681 @default.
- W2022721892 cites W1993059010 @default.
- W2022721892 cites W1998291272 @default.
- W2022721892 cites W2004043229 @default.
- W2022721892 cites W2005128969 @default.
- W2022721892 cites W2007210669 @default.
- W2022721892 cites W2010170880 @default.
- W2022721892 cites W2031107282 @default.
- W2022721892 cites W2031471730 @default.
- W2022721892 cites W2037406174 @default.
- W2022721892 cites W2042650830 @default.
- W2022721892 cites W2050638920 @default.
- W2022721892 cites W2083413823 @default.
- W2022721892 cites W2083523932 @default.
- W2022721892 cites W2084182718 @default.
- W2022721892 cites W2095108154 @default.
- W2022721892 cites W4242611332 @default.
- W2022721892 doi "https://doi.org/10.1063/1.450396" @default.
- W2022721892 hasPublicationYear "1986" @default.
- W2022721892 type Work @default.
- W2022721892 sameAs 2022721892 @default.
- W2022721892 citedByCount "171" @default.
- W2022721892 countsByYear W20227218922012 @default.
- W2022721892 countsByYear W20227218922013 @default.
- W2022721892 countsByYear W20227218922014 @default.
- W2022721892 countsByYear W20227218922015 @default.
- W2022721892 countsByYear W20227218922016 @default.
- W2022721892 countsByYear W20227218922017 @default.
- W2022721892 countsByYear W20227218922018 @default.
- W2022721892 countsByYear W20227218922019 @default.
- W2022721892 countsByYear W20227218922021 @default.
- W2022721892 countsByYear W20227218922022 @default.
- W2022721892 crossrefType "journal-article" @default.
- W2022721892 hasAuthorship W2022721892A5040451729 @default.
- W2022721892 hasAuthorship W2022721892A5044408891 @default.
- W2022721892 hasAuthorship W2022721892A5049991586 @default.
- W2022721892 hasConcept C108036090 @default.
- W2022721892 hasConcept C121332964 @default.
- W2022721892 hasConcept C147789679 @default.
- W2022721892 hasConcept C178790620 @default.
- W2022721892 hasConcept C185544564 @default.
- W2022721892 hasConcept C185592680 @default.
- W2022721892 hasConcept C200447597 @default.
- W2022721892 hasConcept C2779607525 @default.
- W2022721892 hasConcept C2780393986 @default.
- W2022721892 hasConcept C2781066024 @default.
- W2022721892 hasConcept C61048295 @default.
- W2022721892 hasConcept C97355855 @default.
- W2022721892 hasConceptScore W2022721892C108036090 @default.
- W2022721892 hasConceptScore W2022721892C121332964 @default.
- W2022721892 hasConceptScore W2022721892C147789679 @default.
- W2022721892 hasConceptScore W2022721892C178790620 @default.
- W2022721892 hasConceptScore W2022721892C185544564 @default.
- W2022721892 hasConceptScore W2022721892C185592680 @default.
- W2022721892 hasConceptScore W2022721892C200447597 @default.
- W2022721892 hasConceptScore W2022721892C2779607525 @default.
- W2022721892 hasConceptScore W2022721892C2780393986 @default.
- W2022721892 hasConceptScore W2022721892C2781066024 @default.
- W2022721892 hasConceptScore W2022721892C61048295 @default.
- W2022721892 hasConceptScore W2022721892C97355855 @default.
- W2022721892 hasIssue "4" @default.
- W2022721892 hasLocation W20227218921 @default.
- W2022721892 hasOpenAccess W2022721892 @default.
- W2022721892 hasPrimaryLocation W20227218921 @default.
- W2022721892 hasRelatedWork W1562521895 @default.
- W2022721892 hasRelatedWork W1985860357 @default.
- W2022721892 hasRelatedWork W1993707847 @default.
- W2022721892 hasRelatedWork W2031107282 @default.
- W2022721892 hasRelatedWork W2037527647 @default.
- W2022721892 hasRelatedWork W2039460356 @default.
- W2022721892 hasRelatedWork W2046068898 @default.
- W2022721892 hasRelatedWork W2046221493 @default.
- W2022721892 hasRelatedWork W2046874064 @default.
- W2022721892 hasRelatedWork W2078709360 @default.
- W2022721892 hasVolume "84" @default.
- W2022721892 isParatext "false" @default.
- W2022721892 isRetracted "false" @default.
- W2022721892 magId "2022721892" @default.
- W2022721892 workType "article" @default.