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- W2022722492 abstract "The total synthesis of haterumalides NA and B, potent cytotoxic marine macrolides, was achieved by using B-alkyl Suzuki−Miyaura coupling and Nozaki−Hiyama−Kishi coupling as key steps. Compared to our first-generation approach for ent-haterumalide NA methyl ester, this second-generation synthesis yielded much more of the key intermediate. This synthesis established the relative stereochemistry of haterumalide B. Furthermore, the structure−cytotoxicity relationships of haterumalides were investigated. The combination of macrolide and side chain parts proved to be important to the cytotoxicity." @default.
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- W2022722492 date "2009-04-03" @default.
- W2022722492 modified "2023-10-10" @default.
- W2022722492 title "Total Synthesis and Cytotoxicity of Haterumalides NA and B and Their Artificial Analogues" @default.
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- W2022722492 doi "https://doi.org/10.1021/jo802806z" @default.
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