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• W2022730000 abstract "Raman spectra of phosphates of the variscite mineral group, namely strengite, variscite, metavariscite and phosphosiderite, were obtained at 298 and 77 K using a thermal stage and complemented with selected infrared data using a diamond attenuated total reflection cell. Multiple phosphate stretching bands are observed. Bands for strengite at 1006, 1012 and 1026 cm−1 at 298 K and at 997, 1006, 1014 and 1027 cm−1 at 77 K are observed. Variscite is characterized by PO stretching vibrations at 1023, 1005 and 938 cm−1 and phosphosiderite by bands at 1009 and 993 cm−1. These minerals are readily identified by their Raman spectrum both in the PO stretching region and in the low-wavenumber region. Multiple bands attributed to the bending modes of PO4 are identified for each of the minerals. A model is proposed involving non-hydrogen-bonded PO4 and strongly hydrogen-bonded PO4 units together with [Al or Fe(OH)2]+ ·(H2PO4)2−-type species. Raman spectroscopy shows that at the molecular level multiple species of phosphate anions exist for the variscite phosphate minerals. Copyright © 2004 John Wiley & Sons, Ltd." @default.
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• W2022730000 date "2004-01-01" @default.
• W2022730000 modified "2023-10-07" @default.
• W2022730000 title "Raman spectroscopy of phosphates of the variscite mineral group" @default.
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• W2022730000 doi "https://doi.org/10.1002/jrs.1251" @default.
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