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- W2022731401 abstract "The enhanced hydrogen bonding, manifested by significant frequency decreasing of both NH and CO stretching vibrations, is confirmed in a biomedical poly(carbonate urethane) with fluorinated chain extender. It gives rise to preferential association among hard segments and thus promoted microphase separation, which is responsible for the plastic deformation behaviors of the fluorinated poly(carbonate urethane). Furthermore, the segmental orientation, including both soft and hard segments, has been well correlated with the enhanced hydrogen bonding as well as promoted microphase separation. Under stretching large domains are prone to orient with their long axis along tensile direction and thus a negative orientation of hard segments is observed. Meanwhile, decreased orientation of soft segments can also find its origin in the reduced crosslinking density provided by hard domains because of preferential association among hard segments in such a biomedical material. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 2198–2205, 2009" @default.
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- W2022731401 date "2009-10-06" @default.
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- W2022731401 title "Enhanced hydrogen bonding and its dramatic impact on deformation behaviors in a biomedical poly(carbonate urethane) with fluorinated chain extender" @default.
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- W2022731401 doi "https://doi.org/10.1002/polb.21816" @default.
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