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• W2022741083 abstract "MgCl2-supported metallocene catalysts often show peculiar catalytic aspects, which are partially similar to both non-supported complexes and traditional Ziegler–Natta catalysts. In this study, the active-site natures of various MgCl2-supported cyclopentadienyl Ti chloride catalysts are systematically investigated and compared with traditional catalysts in propylene polymerization. The supported titanocene catalysts offer both metallocene-type and Ziegler–Natta-type active-site natures according to the details of the preparation and the activation procedures. The observed dual-active-site natures are plausibly correlated with the valence and charge states of the Ti center." @default.
• W2022741083 created "2016-06-24" @default.
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• W2022741083 date "2013-03-20" @default.
• W2022741083 modified "2023-10-18" @default.
• W2022741083 title "Dual-Active-Site Nature of Magnesium Dichloride-Supported Cyclopentadienyl Titanium Chloride Catalysts Switched by an Activator in Propylene Polymerization" @default.
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• W2022741083 doi "https://doi.org/10.1002/macp.201200662" @default.
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