FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022742217> ?p ?o ?g. }

• W2022742217 endingPage "436" @default.
• W2022742217 startingPage "429" @default.
• W2022742217 abstract "We report the first occurrence of Hf-rich kosnarite [K(Hf,Zr)2(PO4)3], space group R-3c, Z = 6, in the giant Chaquicocha high-sulfidation epithermal gold deposit in the Yanacocha mining district, Peru. Kosnarite crystals are small (<100 μm) and occur in 2–3-mm-thick veins that cut intensively silicified rocks. The paragenesis includes a first stage of As-free pyrite and quartz (plus gratonite and rutile), followed by trace metal-rich pyrite [(Fe,As,Pb,Au)S2] and secondary Fe sulfates. Kosnarite is associated with quartz and is clearly late within the paragenetic sequence. Electron microprobe analyses (EMPA) of kosnarite show relatively high concentrations of HfO2 and Rb2O (7.61 and 1.05 wt.%, respectively). The re-calculated chemical formulas of kosnarite vary from KΣ1.00(Zr1.93Na0.01Hf0.01Mn0.01)Σ1.96(P3.04O4)Σ3 to (K0.92Rb0.05Na0.03)Σ1.00(Zr1.81Hf0.19)Σ2.00 [(P2.98Si0.02As0.01)Σ3.01O4]Σ3, where Hf and Rb are most likely incorporated according to a coupled substitution of Hf4+ + Rb+ ⇔ Zr4+ + K+. Back-scattered electron (BSE) images and elemental mapping of kosnarite reveal that Hf and Rb are enriched in 2–10-μm-wide oscillatory and/or sector zones. High-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) observations of such zones reveal a pattern of alternating, 5–50-nm-thick, Hf-rich and Zr-rich nanozones. These high-resolution observations indicate that the incorporation of Hf does not appear to cause significant distortion in the kosnarite structure. Semiquantitative TEM-energy-dispersive X-ray spectrometry (EDS) analyses of the nano-layers show up to 22 wt.% of HfO2, which corresponds to 31 mol% of the hypothetical, KHf2(PO4)3, end-member. The presence of kosnarite in the advanced argillic alteration zone at Yanacocha is indicative of Hf and Zr mobility under highly acidic conditions and points towards an unforeseen role of phosphates as sinks of Zr and Hf in high-sulfidation epithermal environments. Finally, potentially new geochronological applications of highly insoluble vein kosnarite, including Rb-Sr dating, may provide further age constraints in pervasively altered areas where other isotopic systems might have been reset." @default.
• W2022742217 created "2016-06-24" @default.
• W2022742217 creator A5021670694 @default.
• W2022742217 creator A5030224049 @default.
• W2022742217 creator A5034850692 @default.
• W2022742217 creator A5049928933 @default.
• W2022742217 creator A5064667746 @default.
• W2022742217 creator A5067288937 @default.
• W2022742217 date "2015-04-01" @default.
• W2022742217 modified "2023-10-16" @default.
• W2022742217 title "Constraints on Hf and Zr mobility in high-sulfidation epithermal systems: formation of kosnarite, KZr2(PO4)3, in the Chaquicocha gold deposit, Yanacocha district, Peru" @default.
• W2022742217 cites W1968731413 @default.
• W2022742217 cites W1973124747 @default.
• W2022742217 cites W1977393817 @default.
• W2022742217 cites W2038019149 @default.
• W2022742217 cites W2049913504 @default.
• W2022742217 cites W2087035217 @default.
• W2022742217 cites W2092156812 @default.
• W2022742217 cites W2094889210 @default.
• W2022742217 cites W2111473359 @default.
• W2022742217 cites W2114997760 @default.
• W2022742217 cites W2141937448 @default.
• W2022742217 cites W2146026511 @default.
• W2022742217 cites W2147529806 @default.
• W2022742217 cites W2329837689 @default.
• W2022742217 cites W2385435147 @default.
• W2022742217 cites W34831761 @default.
• W2022742217 cites W4245989904 @default.
• W2022742217 doi "https://doi.org/10.1007/s00126-015-0586-z" @default.
• W2022742217 hasPublicationYear "2015" @default.
• W2022742217 type Work @default.
• W2022742217 sameAs 2022742217 @default.
• W2022742217 citedByCount "2" @default.
• W2022742217 countsByYear W20227422172017 @default.
• W2022742217 countsByYear W20227422172020 @default.
• W2022742217 crossrefType "journal-article" @default.
• W2022742217 hasAuthorship W2022742217A5021670694 @default.
• W2022742217 hasAuthorship W2022742217A5030224049 @default.
• W2022742217 hasAuthorship W2022742217A5034850692 @default.
• W2022742217 hasAuthorship W2022742217A5049928933 @default.
• W2022742217 hasAuthorship W2022742217A5064667746 @default.
• W2022742217 hasAuthorship W2022742217A5067288937 @default.
• W2022742217 hasBestOaLocation W20227422172 @default.
• W2022742217 hasConcept C113196181 @default.
• W2022742217 hasConcept C127313418 @default.
• W2022742217 hasConcept C138411078 @default.
• W2022742217 hasConcept C151730666 @default.
• W2022742217 hasConcept C154401813 @default.
• W2022742217 hasConcept C17409809 @default.
• W2022742217 hasConcept C185592680 @default.
• W2022742217 hasConcept C191897082 @default.
• W2022742217 hasConcept C192562407 @default.
• W2022742217 hasConcept C199289684 @default.
• W2022742217 hasConcept C26687426 @default.
• W2022742217 hasConcept C2776062231 @default.
• W2022742217 hasConcept C2777889555 @default.
• W2022742217 hasConcept C2778480967 @default.
• W2022742217 hasConcept C2779870107 @default.
• W2022742217 hasConcept C2780596425 @default.
• W2022742217 hasConcept C2780652884 @default.
• W2022742217 hasConcept C43617362 @default.
• W2022742217 hasConcept C518881349 @default.
• W2022742217 hasConcept C8010536 @default.
• W2022742217 hasConceptScore W2022742217C113196181 @default.
• W2022742217 hasConceptScore W2022742217C127313418 @default.
• W2022742217 hasConceptScore W2022742217C138411078 @default.
• W2022742217 hasConceptScore W2022742217C151730666 @default.
• W2022742217 hasConceptScore W2022742217C154401813 @default.
• W2022742217 hasConceptScore W2022742217C17409809 @default.
• W2022742217 hasConceptScore W2022742217C185592680 @default.
• W2022742217 hasConceptScore W2022742217C191897082 @default.
• W2022742217 hasConceptScore W2022742217C192562407 @default.
• W2022742217 hasConceptScore W2022742217C199289684 @default.
• W2022742217 hasConceptScore W2022742217C26687426 @default.
• W2022742217 hasConceptScore W2022742217C2776062231 @default.
• W2022742217 hasConceptScore W2022742217C2777889555 @default.
• W2022742217 hasConceptScore W2022742217C2778480967 @default.
• W2022742217 hasConceptScore W2022742217C2779870107 @default.
• W2022742217 hasConceptScore W2022742217C2780596425 @default.
• W2022742217 hasConceptScore W2022742217C2780652884 @default.
• W2022742217 hasConceptScore W2022742217C43617362 @default.
• W2022742217 hasConceptScore W2022742217C518881349 @default.
• W2022742217 hasConceptScore W2022742217C8010536 @default.
• W2022742217 hasIssue "4" @default.
• W2022742217 hasLocation W20227422171 @default.
• W2022742217 hasLocation W20227422172 @default.
• W2022742217 hasOpenAccess W2022742217 @default.
• W2022742217 hasPrimaryLocation W20227422171 @default.
• W2022742217 hasRelatedWork W1491463649 @default.
• W2022742217 hasRelatedWork W2011313875 @default.
• W2022742217 hasRelatedWork W2016811984 @default.
• W2022742217 hasRelatedWork W2022742217 @default.
• W2022742217 hasRelatedWork W2024263520 @default.
• W2022742217 hasRelatedWork W2041389048 @default.
• W2022742217 hasRelatedWork W2051403823 @default.
• W2022742217 hasRelatedWork W2547871940 @default.
• W2022742217 hasRelatedWork W3008690468 @default.
• W2022742217 hasRelatedWork W3116484877 @default.

• next