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• W2022743316 abstract "Chromium and iron K-edge extended X-ray absorption fine structure (EXAFS) and X-ray absorption near-edge structure (XANES) measurements for several phases in the Sr2CrxFe2 –xO5 +y system have established that there are substantial numbers of chromium atoms with either short (ca. 1.65 Å) or long (ca. 1.91 Å) distances to oxygen. These can be attributed to high oxidation states of chromium in tetrahedral co-ordination and Cr3+ ions in octahedral co-ordination, respectively. There is also some evidence for chromium in edge-sharing polyhedra, but not in face-sharing polyhedra, while the iron is in corner-sharing polyhedra. Possible model structures for the 15R phase are discussed." @default.
• W2022743316 created "2016-06-24" @default.
• W2022743316 creator A5058855895 @default.
• W2022743316 date "1992-01-01" @default.
• W2022743316 modified "2023-09-25" @default.
• W2022743316 title "Determination of co-ordination numbers and oxidation states in chromium oxides by extended X-ray absorption fine structure spectroscopy" @default.
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• W2022743316 doi "https://doi.org/10.1039/jm9920200057" @default.
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