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- W2022744052 abstract "Die Titelverbindungen entstanden durch Hydrolyse bzw. Oxidation aus Amino- und Thioderivaten der Quadratsäure in Gegenwart von LaIII- und BiIII-Ionen. Beide Verbindungen kristallisieren als dreidimensionale Koordinationspolymere, wie Röntgenstrukturanalysen an Einkristallen zeigten. In La2(C2O4)(C4O4)2(H2O)8 · 2.5 H2O sind Oxalat-verbrückte Paare von LaO9-Polyedern miteinander über Quadratationen verbunden. In K[Bi(C2O4)2] · 5 H2O ist jedes Bi-Atom über bisbidentate Oxalationen mit vier benachbarten Bi-Atomen verbunden. Dadurch entsteht eine diamantartige Topologie mit quadratischen Kanälen. Die Kanäle sind in beiden Verbindungen partiell mit Wassermolekülen gefüllt. Oxalato- and Squarato-Bridged Threedimensional Networks: The Crystal Structures of La2(C2O4)(C4O4)2(H2O)8 · 2.5 H2O and K[Bi(C2O4)2] · 5 H2O The title compounds have been formed by hydrolysis of amino- and thioderivatives of squaric acid in the presence of LaIII and BiIII ions. Both compounds are threedimensional coordination polymers in the solid state, as shown by single crystal X-ray crystallography. In La2(C2O4)(C4O4)2(H2O)8 · 2.5 H2O oxalato-bridged pairs of LaO9 polyhedra are connected with identical neighbouring polyhedra by squarate ions. In K[Bi(C2O4)2] · 5 H2O each Bi atom is fourfold linked to other Bi atoms by the oxalate ions. The resulting 3D network shows a diamond-like topology with square-shaped channels. In both structures the channels are partially filled by water molecules." @default.
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- W2022744052 date "2001-09-01" @default.
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- W2022744052 title "Oxalato- und Quadratato-Komplexe hochkoordinierter Metallionen: Die Raumnetzstrukturen von La2(C2O4)(C4O4)2(H2O)8 · 2,5 H2O und K[Bi(C2O4)2] · 5 H2O" @default.
- W2022744052 doi "https://doi.org/10.1002/1521-3749(200109)627:9<2173::aid-zaac2173>3.0.co;2-l" @default.
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